What heros to use when defending, Titans, or quests, etc, etc

I am trying to figure out what heros to use for different parts of the game. I am not yet familiar with all if the heros, I think I have a pretty good mission team, they do pretty good at everything else, but where I am running in to trouble mostly is the events like the current one we have going on. I am completely lost and trying to find a guide or anything like that, that can lead me to the information I seak.

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