One-man Alliance?

You need a specific alliance score first before your alliance participates in wars. Although I don’t remember the specific number, but it’s low enough that killing your first titan will let you.
EDIT: confirmed that the alliance score required to participate is quite low but does exist: 1.10.3/1.10.4 Update & Alliance Wars Status (16 Mar)

  • Minimum alliance score to participate in the war raised to 3250

The loot for A+ against a 1* titan is:
1 + 3 = loot tier 4.

For reference, if a 7* titan escapes and you get B grade:
(7 + 1) / 2 = loot tier 4.

So yeah lol, the loot for a 1* titan is bad. Source: Titans: Grades, Loot Tiers, and You

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